Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

Jiao Gui; Haisheng Xie; Fengjuan Chen; Zhipeng Liu; Xiaoqi Zhang; Fubin Jiang; Wei Zeng

doi:10.1039/C9OB02457C

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Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines†

Jiao Gui,^a Haisheng Xie,^a Fengjuan Chen,^a Zhipeng Liu,^a Xiaoqi Zhang,

^b Fubin Jiang^c and Wei Zeng

*^a

Author affiliations

* Corresponding authors

^a China Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China
E-mail: zengwei@scut.edu.cn

^b Guangdong Provincial Engineering Research Center for Modernization of TCM, College of Pharmacy, Jinan University, Guangzhou 510632, China

^c College of Chemistry, Beijing Normal University, Beijing 100875, China

Abstract

A Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines in the presence of TPT and CF₃CO₂H has been developed. This transformation provides a green approach to alpha-amino-substituted arylalkanes under metal-free conditions.

This article is part of the themed collection: Synthetic methodology in OBC

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Article information

DOI: https://doi.org/10.1039/C9OB02457C
Article type: Paper
Submitted: 14 Nov 2019
Accepted: 26 Dec 2019
First published: 26 Dec 2019

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Org. Biomol. Chem., 2020,18, 956-963

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Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

J. Gui, H. Xie, F. Chen, Z. Liu, X. Zhang, F. Jiang and W. Zeng, Org. Biomol. Chem., 2020, 18, 956 DOI: 10.1039/C9OB02457C

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Organic & Biomolecular Chemistry

Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines†

Abstract

Supplementary files

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Brønsted acid/visible-light-promoted Markovnikov hydroamination of vinylarenes with arylamines

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