Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF3SO2Na

Wenhao Long; Pengcheng Lian; Jingjing Li; Xiaobing Wan

doi:10.1039/D0OB01322F

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Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF₃SO₂Na†

Wenhao Long,^a Pengcheng Lian,^a Jingjing Li^a and Xiaobing Wan

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: wanxb@suda.edu.cn

Abstract

This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac)₃. The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance.

This article is part of the themed collection: Catalysis & biocatalysis in OBC

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Article information

DOI: https://doi.org/10.1039/D0OB01322F
Article type: Communication
Submitted: 28 Jun 2020
Accepted: 31 Jul 2020
First published: 03 Aug 2020

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Org. Biomol. Chem., 2020,18, 6483-6486

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Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF₃SO₂Na

W. Long, P. Lian, J. Li and X. Wan, Org. Biomol. Chem., 2020, 18, 6483 DOI: 10.1039/D0OB01322F

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Organic & Biomolecular Chemistry