Issue 42, 2020
From the journal:

Organic & Biomolecular Chemistry

Rhodium(iii)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides†

Somaraju Yugandar,a   Taiki Moritaa  and  Hiroyuki Nakamura ORCID logo *a  

* Corresponding authors

a Laboratory of Chemistry and Life Science, Innovative Institute of Research Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan
E-mail: hiro@res.titech.ac.jp

Abstract

Decarboxylative C–H functionalization of isoxazoles with electron-deficient alkenes and sulfoxonium ylides at the C5 position was achieved in the presence of rhodium(III) catalysts to give the corresponding alkenylation and acylmethylation products, respectively.

Graphical abstract: Rhodium(iii)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides

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Article information

DOI
https://doi.org/10.1039/D0OB02027C
Article type
Communication
Submitted
04 Oct 2020
Accepted
15 Oct 2020
First published
20 Oct 2020

Org. Biomol. Chem., 2020,18, 8625-8628

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Rhodium(III)-catalysed decarboxylative C–H functionalization of isoxazoles with alkenes and sulfoxonium ylides

S. Yugandar, T. Morita and H. Nakamura, Org. Biomol. Chem., 2020, 18, 8625 DOI: 10.1039/D0OB02027C

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