Issue 47, 2020

Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions

Abstract

Herein we propose an auto-tandem catalytic approach towards the preparation of poly(ester–ether)s from simple alkyl acrylates and diols. By combining oxa-Michael addition with transesterification the preparation of hydroxy functionalised acrylate monomers can be avoided.

Graphical abstract: Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions

Supplementary files

Article information

Article type
Communication
Submitted
05 Sep 2020
Accepted
21 Nov 2020
First published
23 Nov 2020
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2020,11, 7476-7480

Step-growth polymerisation of alkyl acrylates via concomitant oxa-Michael and transesterification reactions

K. Ratzenböck, D. Pahovnik and C. Slugovc, Polym. Chem., 2020, 11, 7476 DOI: 10.1039/D0PY01271H

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