Issue 8, 2020
From the journal:

Inorganic Chemistry Frontiers

Anisotropic proton conduction realized by a layered vanadium selenite single crystal†

Hai-Yan Sun, ORCID logo ab   Shi-Hao Sun,ab   Bing Hu, ORCID logo b   Liao-Kuo Gong,b   Yan-Min Zou,b   Ji-Long Li,ab   Mei-Ling Feng ORCID logo *b  and  Xiao-Ying Huang ORCID logo b  

* Corresponding authors

a College of Chemistry and Materials Science, Fujian Normal University, No. 8 Shangsan Road, Fuzhou 350007, China

b State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
E-mail: fml@fjirsm.ac.cn

Abstract

The study of anisotropic proton conduction (APC) on a layered-structured vanadium selenite single crystal, namely [H3O][(VO2)3(SeO3)2] (1), reveals the proton conductivity (σ) ratio (σ[100]/σ[001] = 188) at 80 °C under 70% relative humidity (RH) and the proton conduction mechanisms of Grotthuss and Vehicle along the [100] and [001] directions, respectively.

Graphical abstract: Anisotropic proton conduction realized by a layered vanadium selenite single crystal

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Article information

DOI
https://doi.org/10.1039/D0QI00040J
Article type
Research Article
Submitted
13 Jan 2020
Accepted
05 Mar 2020
First published
10 Mar 2020

Inorg. Chem. Front., 2020,7, 1699-1703

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Anisotropic proton conduction realized by a layered vanadium selenite single crystal

H. Sun, S. Sun, B. Hu, L. Gong, Y. Zou, J. Li, M. Feng and X. Huang, Inorg. Chem. Front., 2020, 7, 1699 DOI: 10.1039/D0QI00040J

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