In situ synthesis of Cl-doped Bi2O2CO3 and its enhancement of photocatalytic activity by inducing generation of oxygen vacancies

Abstract

In this paper, a novel ionic liquid-assisted solvothermal method to prepare Cl-doped bismuth oxycarbonate (Bi₂O₂CO₃) is presented. The ionic liquid of [Hnmp]Cl not only enhances the solvothermal process to help the formation of Bi₂O₂CO₃, but also provides chloride element as a dopant. XRD and XPS show that all three samples are Bi₂O₂CO₃ with high purity. XPS, solid EPR, and TEM results prove that Cl is doped into the Bi₂O₂CO₃ lattice and oxygen vacancies are generated. DRS results show that after Cl doping, the absorption of visible light by Bi₂O₂CO₃ is enhanced. Surface photovoltage (SPV) and transient photocurrent tests show that as the doping amount of Cl increases, the separation efficiency of photogenerated electron–hole pairs over Bi₂O₂CO₃ improves. The photocatalytic activity of Bi₂O₂CO₃ is evaluated by the degradation of rhodamine B, which is increased after Cl doping. This work would broaden the application of ionic liquids in the solvothermal process and deepen the understanding of anionic ion doping in Bi₂O₂CO₃.