Issue 1, 2020
From the journal:

Organic Chemistry Frontiers

Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines†

Yao Zhou, ORCID logo a   Ya Wang,a   Zhiyi Song, ORCID logo b   Tamaki Nakano ORCID logo b  and  Qiuling Song ORCID logo *ac  

* Corresponding authors

a Institute of Next Generation Matter Transformation, College of Materials Science & Engineering and College of Chemical Engineering at Huaqiao University, 668 Jimei Blvd, Xiamen, Fujian, P. R. China
E-mail: qsong@hqu.edu.cn
Fax: +86-592-6162990

b Institute for Catalysis (ICAT), Hokkaido university, N 21, W 10, Kita-ku, Sapporo 001-0021, Japan

c Fujian University Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, Fuzhou, Fujian, China

Abstract

The Cu-catalyzed C–H arylation of enamines via the oxidative C–N cleavage of 3-aminoindazoles is presented. A diverse array of arylated enamines were produced in decent yields with a wide substrate scope under mild conditions. Here, 3-aminoindazoles were harnessed as novel arylating agents via a radical process.

Graphical abstract: Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9QO01177C
Article type
Research Article
Submitted
24 Sep 2019
Accepted
24 Oct 2019
First published
01 Nov 2019

Org. Chem. Front., 2020,7, 25-29

Permissions

Request permissions

Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines

Y. Zhou, Y. Wang, Z. Song, T. Nakano and Q. Song, Org. Chem. Front., 2020, 7, 25 DOI: 10.1039/C9QO01177C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements