Issue 6, 2020
From the journal:

Organic Chemistry Frontiers

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters†

Xinxin Qi,a   Zhi-Peng Baoa  and  Xiao-Feng Wu ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Zhejiang Sci-Tech University, Xiasha Campus, Hangzhou 310018, People's Republic of China
E-mail: xiao-feng.wu@catalysis.de

b Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Straβe 29a, 18059 Rostock, Germany

Abstract

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides has been studied. Both aryl and alkyl sulfonyl chlorides were all successfully transformed into the desired thioesters with sulfonyl chlorides as the sulfur source. Mo(CO)6 played a dual role as both CO surrogate and reductant in this reaction.

Graphical abstract: Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

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Article information

DOI
https://doi.org/10.1039/D0QO00158A
Article type
Research Article
Submitted
02 Feb 2020
Accepted
25 Feb 2020
First published
26 Feb 2020

Org. Chem. Front., 2020,7, 885-889

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Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

X. Qi, Z. Bao and X. Wu, Org. Chem. Front., 2020, 7, 885 DOI: 10.1039/D0QO00158A

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