Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

Xin Chen; Dongdong Qi; Chao Liu; Hailong Wang; Zheng Xie; Tse-Wei Chen; Shen-Ming Chen; Tien-Wen Tseng; Jianzhuang Jiang

doi:10.1039/C9RA07847A

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Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds†

Xin Chen,‡^a Dongdong Qi,‡^a Chao Liu,^a Hailong Wang,*^a Zheng Xie,

^b Tse-Wei Chen,^c Shen-Ming Chen,*^c Tien-Wen Tseng

*^c and Jianzhuang Jiang

*^a

Author affiliations

* Corresponding authors

^a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn

^b Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Science, Beijing 100190, China

^c Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan

Abstract

Electrochemical and theoretical investigations over triple-quadruple-, quintuple-, and sextuple-decker sandwich-type compounds {[(Pc*)Sm][(Pc*)Cd_n(Pc*)_n][Sm(Pc*)]} (n = 0–3) elucidate successive π–π interaction-linked extension in the perpendicular direction of the phthalocyanine plane along with increasing the stacked tetrapyrrole number, significantly improving the nonlinear optical properties including effective imaginary third order molecular hyperpolarizability and optical limiting threshold.

This article is part of the themed collection: Editors' Collection: Phthalocyanines

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DOI: https://doi.org/10.1039/C9RA07847A
Article type: Paper
Submitted: 27 Sep 2019
Accepted: 18 Dec 2019
First published: 02 Jan 2020
This article is Open Access

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RSC Adv., 2020,10, 317-322

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Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

X. Chen, D. Qi, C. Liu, H. Wang, Z. Xie, T. Chen, S. Chen, T. Tseng and J. Jiang, RSC Adv., 2020, 10, 317 DOI: 10.1039/C9RA07847A

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Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds†

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Elucidating π–π interaction-induced extension effect in sandwich phthalocyaninato compounds

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