Comparative study on the catalytic steam reforming of biomass pyrolysis oil and its derivatives for hydrogen production

Abstract

In order to explore the reforming process of biomass pyrolysis oil in depth, the catalytic steam reforming (SR) of crude bio-oil (BIO) derived from rapid pyrolysis of rice husk and its derivatives for hydrogen production was studied by means of a bench-scale fixed-bed unit combined with the FTIR/TCD technique. The physico-chemical properties and compositions of BIO were determined. Acetic acid (HOAc), ethylene glycol (EG), acetone (ACE) and phenol (PHE) were selected as four representative bio-oil derivatives. Evolution characteristics of H₂, CO, CO₂ and CH₄ during SR of HOAc, EG, ACE, PHE and BIO were revealed and compared. The hydrogen yield increased sharply with reaction time to the peak values of 24.7%, 32.3%, 16.4%, 25.6% and 24.9%, corresponding to HOAc, EG, ACE, PHE and BIO, respectively. After that, the yield of hydrogen exhibited a downward trend, suggesting that the catalyst ability for selective hydrogen production gradually decreased. The H₂ yield from EG was the highest, followed by PHE, HOAc, BIO and ACE. The order of CO yields from large to small was EG > HOAc > ACE > BIO ≈ PHE. The percentages of coke deposited on catalyst were arranged in descending order as HOAc > BIO > ACE > PHE > EG. This study could provide more detailed information on the catalytic reforming mechanism of bio-oil on the one hand, and also point out the direction for the improvement of the catalysts, which play a role in ensuring the high yield of H₂ while converting CO to H₂ through the water gas shift reaction.