Room temperature blooming of CeO2 3D nanoflowers under sonication and catalytic efficacy towards CO conversion

Abstract

Carbon monoxide (CO), being a highly toxic gas, bears hazardous effects on human health and contributes majorly to environmental pollution. It is mostly produced by automobile exhausts and incomplete combustion of carbon-containing substances. Thus, the development of catalysts for CO conversion is highly imperative and has always gained interest for real field applications. Besides the high oxygen storage capacity and facile transitions between oxidation states, the huge abundance of cerium on earth makes CeO₂ a low-cost and highly effective alternative to noble metal catalysts for CO oxidation. The present work delineates the room temperature synthesis of flower-shaped 3D CeO₂ nanostructures using a sonication-assisted simple synthesis method within 2 hours under the pivotal importance of a structure-directing agent, polyvinylpyrrolidone (PVP). The bifunctional contributions of PVP as a surfactant and as a capping agent are discussed with a plausible mechanism. The method leading to the formation of hierarchical CeO₂ nanoflowers provides an appreciable surface area of 132.69 cm² g⁻¹. The morphological and structural characterizations of the catalyst were thoroughly investigated using FESEM, TEM, XRD, UV-visible spectroscopy, photoluminescence spectroscopy, FTIR spectroscopy and X-ray photoelectron spectroscopy. The structural efficacies of flower-like CeO₂ nanostructures have also been correlated to the narrowing of the band gap and the generation of the corresponding oxygen vacancies, resulting in surface catalytic properties towards 80% conversion of CO.