Treatment of oil refinery effluent using bio-adsorbent developed from activated palm kernel shell and zeolite

Abstract

This study investigated the potential of palm kernel shell (PKS) as a biomass feed for adsorbent production. This work aims at synthesizing green adsorbent from activated PKS by integrating iron oxide and zeolite. The newly developed adsorbents, zeolite-Fe/AC and Fe/AC, were analyzed for surface area, chemical composition, magnetic properties, crystallinity, and stability. The adsorbent efficiency in removing effluent from the palm oil mill was evaluated. The influence of operating parameters, including adsorbent dosage, H₂O₂, reaction time, and initial solution pH for adsorption performance was studied. The Fourier transform infrared analysis revealed that the adsorbents contain functional groups including OH, N–H, CO and CC, which are essential for removing pollutants. The SEM-EDX analysis shows holes in the adsorbent surface and that it is smooth. The adsorption study revealed that under optimized conditions, by using 4 g L⁻¹ of adsorbent and 67.7 mM H₂O₂, zeolite-Fe/AC was able to remove 83.1% colour and 67.2% COD within 30 min. However, Fe/AC requires 5 g L⁻¹ of adsorbent and 87.7 mM to remove 86.8 percent and 65.6 percent, respectively. This study also showed that zeolite-Fe/AC has higher reusability compared to Fe/AC. Among Freundlich and Temkin models, the experimental data were found to be best fitted with the Langmuir isotherm model. The kinetic analysis revealed that for both adsorbents, the adsorption process fitted the pseudo-second-order model (R² = 0.9724). The finding reflects monolayer adsorption of zeolite-Fe/AC and Fe/AC. This study thus demonstrates the applicability of low-cost green adsorbents produced from PKS to treat oil refinery effluent and other recalcitrant wastewaters.