Issue 30, 2020, Issue in Progress
From the journal:

RSC Advances

Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes†

Yi Chen,ab   Liqing Ai,ab   Yongming Lia  and  Caihong Xu ORCID logo *ab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: caihong@iccas.ac.cn

b University of Chinese Academy of Sciences, Beijing, P. R. China

Abstract

Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with LiBH4 as catalyst. A possible mechanism was proposed to explain the redistribution process.

Graphical abstract: Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0RA03536J
Article type
Paper
Submitted
19 Mar 2020
Accepted
27 Apr 2020
First published
05 May 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 17404-17407

Permissions

Request permissions

Borohydride catalyzed redistribution reaction of hydrosilane and chlorosilane: a potential system for facile preparation of hydrochlorosilanes

Y. Chen, L. Ai, Y. Li and C. Xu, RSC Adv., 2020, 10, 17404 DOI: 10.1039/D0RA03536J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements