Synthesis of hierarchical MgO based on a cotton template and its adsorption properties for efficient treatment of oilfield wastewater

Abstract

A biomorphic MgO nanomaterial was fabricated via a facile and low-cost immersion method using cotton as the template. The obtained materials were characterized via X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and N₂ adsorption–desorption analysis. The as-prepared MgO retained the structure of cotton, with a porous hierarchical structure and a high specific surface area, which endowed it with great potential due to its excellent adsorption properties for the adsorption of additives in oil field wastewater. It also exhibited the maximum adsorption capacity of 391.36 mg g⁻¹ for sulfonated lignite. The adsorption process of sulfonated lignite on biomorphic MgO was systematically investigated and was found to obey the pseudo-second-order rate equation and the Langmuir adsorption model. The negative values of Gibbs free energy change (ΔG) showed that the adsorption process was feasible and spontaneous. The endothermic process was depicted with a positive value for ΔH.