Issue 47, 2020, Issue in Progress
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RSC Advances

Modulator-free approach towards missing-cluster defect formation in Zr-based UiO-66†

Patchanee Chammingkwan, ORCID logo a   Goji Yildun Shangkum,ab   Le Thi Tuyet Mai,a   Priyank Mohan,a   Ashutosh Thakur,a   Toru Wada ORCID logo a  and  Toshiaki Taniike*a  

* Corresponding authors

a Graduate School of Advanced Science and Technology, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan
E-mail: taniike@jaist.ac.jp

b Department of Chemistry, Faculty of Natural Sciences, University of Jos, Jos Plateau State, Nigeria

Abstract

By rigorous control of water, missing-cluster defects in Zr-based UiO-66 were generated to a remarkable extent without the need of acidic modulators. The presence of missing-cluster defects created hierarchical pore structures, which had a profound effect on the catalytic performance.

Graphical abstract: Modulator-free approach towards missing-cluster defect formation in Zr-based UiO-66

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Article information

DOI
https://doi.org/10.1039/D0RA04812G
Article type
Paper
Submitted
01 Jun 2020
Accepted
17 Jul 2020
First published
28 Jul 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 28180-28185

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Modulator-free approach towards missing-cluster defect formation in Zr-based UiO-66

P. Chammingkwan, G. Y. Shangkum, L. T. T. Mai, P. Mohan, A. Thakur, T. Wada and T. Taniike, RSC Adv., 2020, 10, 28180 DOI: 10.1039/D0RA04812G

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