Synthesis of 2D cobalt oxide nanosheets using a room temperature liquid metal

Abstract

Room temperature liquid metals based on Ga can be used as a synthesis medium for the creation of metal oxide nanomaterials, however one thermodynamic limitation is that metals that are more easily oxidised than Ga are required to ensure their preferential formation. In this work we demonstrate a proof of principle approach whereby exposing the liquid metal alloyed with the required metal to acidic conditions circumvents preferential formation of Ga₂O₃ and allows for the formation of the required 2D transition metal oxide nanosheets. The synthesis procedure is straightforward in that it only requires bubbling oxygen gas through the liquid metal alloy into a solution of 10 mM HCl. We show that the formation of thin nanosheets of ca. 1 nm in thickness of CoO is possible. The material is characterised using transmission electron microscopy, atomic force microscopy, X-ray photoelectron and Raman spectroscopy. The electrocatalytic activity of the CoO nanosheets was investigated for the oxygen evolution reaction where the nanosheet thickness was found to be a factor influencing the activity. This proof of principle offers a route to the possible formation of many other 2D transition metal oxides from metals that are less readily oxidised than Ga by taking advantage of the interesting properties of room temperature liquid metals.