Issue 58, 2020, Issue in Progress
From the journal:

RSC Advances

Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex†

Licheng Zhan,a   Gengtao Zhang,a   Jiwei Wanga  and  Jun Zhang ORCID logo *a  

* Corresponding authors

a Key Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
E-mail: zhangj@ecust.edu.cn

Abstract

Four tetrahydroquinoline-based chiral carbene precursors were synthesized using unsymmetrical N,N′-diarylformamidines and chiral 2-allyloxiranes as starting materials. A representative NHC–gold complex has been prepared and fully characterized, the crystal structure of which reveals an intramolecular Au⋯H–C(sp3) interaction between Au(I) and the hydrogen atom of the isopropyl moiety in the N-aryl group.

Graphical abstract: Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(i) complex

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Article information

DOI
https://doi.org/10.1039/D0RA07271K
Article type
Paper
Submitted
24 Aug 2020
Accepted
09 Sep 2020
First published
23 Sep 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 35253-35256

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Syntheses of tetrahydroquinoline-based chiral carbene precursors and the related chiral NHC–Au(I) complex

L. Zhan, G. Zhang, J. Wang and J. Zhang, RSC Adv., 2020, 10, 35253 DOI: 10.1039/D0RA07271K

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