Preparation of antistatic epoxy resin coatings based on double comb-like quaternary ammonium salt polymers

Abstract

Two kinds of double comb-like quaternary ammonium salt polymers P(DPA-EPI) and P(DBA-EPI) with lower polarity were designed and synthesized using epichlorohydrin (EPI), di-n-propylamine (DPA) and di-n-butylamine (DBA) as raw materials. The transparent antistatic epoxy resin coatings were obtained using the two polymers as antistatic agents, respectively. Because P(DPA-EPI) and P(DBA-EPI) with good hygroscopic performance are easily dissolved in epoxy resin paints and are nearly linearly arranged in the epoxy resin paints, the obtained transparent antistatic epoxy resin coatings achieve good antistatic properties. The values of ρ_s of the coatings reach 5.13 × 10⁸ Ω sq⁻¹ and 2.69 × 10⁸ Ω sq⁻¹, respectively, with a lower addition amount of polymers of only 1.0 wt%. The two antistatic epoxy resin coatings also have good durability. Compared to the epoxy resin coating, with the introduction of P(DPA-EPI) and P(DBA-EPI), the thermal stability and adhesion of the antistatic epoxy resin coatings do not change obviously, but the Rockwell hardness values slightly reduce.