Issue 62, 2020

Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl3

Abstract

Herein, we report a ring-opening 1,3-arylboration of aryl cyclopropanes using BCl3 in the presence of arene nucleophiles. Formal 1,3-oxy arylation and 1,3-amino arylation of the arylcyclopropane via one-pot derivatization of the installed boron group were also achieved.

Graphical abstract: Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl3

Supplementary files

Article information

Article type
Paper
Submitted
31 Aug 2020
Accepted
07 Oct 2020
First published
13 Oct 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 37797-37799

Ring-opening 1,3-arylboration of arylcyclopropanes mediated by BCl3

Y. Kuboki, M. Arisawa and K. Murai, RSC Adv., 2020, 10, 37797 DOI: 10.1039/D0RA08151E

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