Construction of magnetic MgFe2O4/CdS/MoS2 ternary nanocomposite supported on NaY zeolite and highly efficient sonocatalytic degradation of organic pollutants

Abstract

In this work, the novel magnetically separable NaY zeolite/MgFe₂O₄/CdS nanorods/MoS₂ nanoflowers nanocomposite was successfully synthesized through the ultrasonic-assisted solvothermal approach. FESEM, EDAX, XRD, FTIR, TEM, AFM, VSM, N₂-BET, UV-vis DRS and PL were utilized to identify the as-synthesized nanocomposite. Subsequently, the sonocatalytic activity of this nanocomposite was assessed in the degradation of organic dyes, including methylene blue (MB), rhodamine B (RhB) and methyl orange (MO) from water solutions for the first time. Several analytical parameters like irradiation time, process type, initial MB concentration, H₂O₂ concentration, catalyst dosage, organic dye type, and US power have been systematically investigated to attain the maximum sonocatalytic yield. Regarding the acquired data, the NaY/MgFe₂O₄/CdS NRs/MoS₂ NFs sonocatalyst was incredibly able to completely eliminate the MB via engaging the US/H₂O₂ system. The kinetic evaluates demonstrated the sonodegradation reactions of the MB followed a first-order model. The apparent rate constant (k_app) and half-life time (t_1/2) acquired for the sonodegradation process of MB utilizing the US/H₂O₂/NaY/MgFe₂O₄/CdS NRs/MoS₂ NFs system were measured to be 1.162 min and 0.596 min⁻¹, respectively. The free ˙OH radicals were also recognized as the main reactive oxygen species in the MB sonodegradation process under US irradiation. In addition, the outcomes of the recyclability study of the NaY/MgFe₂O₄/CdS NRs/MoS₂ NFs sonocatalytic clearly displayed a less than 6% drop of the catalytic activity in up to four sequential runs. Lastly, a plausible mechanism for the sonodegradation reaction of organic dyes was suggested and discussed.