A pH-stable Ag(i) multifunctional luminescent sensor for the efficient detection of organic solvents, organochlorine pesticides and heavy metal ions

Abstract

Developing novel luminescent materials for sensitive and rapid detection of heavy metal ions, organic solvents and organochlorine pesticides is vital for environmental monitoring. Herein, a new Ag(I) luminescent coordination polymer [Ag(3-dpyb)(H₃odpa)]·H₂O (LCP 1) (3-dpyb = N,N′-bis(3-pyridinecarboxamide)-1,4-butane, H₄odpa = 4,4′-oxydiphthalic acid) was obtained by a hydrothermal reaction and characterized by single crystal, powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis and luminescence spectroscopy. LCP 1 is a three-dimensional (3D) supramolecular framework formed from 1D [Ag-3-dpyb-H₃odpa]_n chains and H-bond interactions. The luminescence sensing study of LCP 1 for recognizing organic solvents, organochlorine pesticides and heavy metal ions was performed, which demonstrated it to be a potential luminescent sensor for Hacac, NB, 2,6-DCN, Fe²⁺, Hg²⁺, and Fe³⁺. Fe²⁺, Hg²⁺, and Fe³⁺ in river water were determined using LCP 1 with satisfying recovery.