Issue 72, 2020, Issue in Progress
From the journal:

RSC Advances

Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes†

Jonathon P. Matheny,a   Pavel M. Yamanushkin,a   Peter A. Petillob  and  Michael Rubin ORCID logo *ac  

* Corresponding authors

a Department of Chemistry, University of Kansas, 1567 Irving Hill Road, Lawrence, KS 66045-7582, USA
E-mail: mrubin@ku.edu
Fax: +1-785-864-5396
Tel: +1-785-864-5071

b Design-Zyme LLC, 4950 Research Park Way, Lawrence, KS 66047, USA

c Department of Chemistry, North Caucasus Federal University, 1a Pushkin St., Stavropol 355009, Russian Federation
E-mail: alexaks05@rambler.ru

Abstract

The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal-templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.

Graphical abstract: Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes

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Article information

DOI
https://doi.org/10.1039/D0RA09014J
Article type
Paper
Submitted
22 Oct 2020
Accepted
05 Dec 2020
First published
15 Dec 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 44183-44190

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Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes

J. P. Matheny, P. M. Yamanushkin, P. A. Petillo and M. Rubin, RSC Adv., 2020, 10, 44183 DOI: 10.1039/D0RA09014J

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