Issue 39, 2020

Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

Abstract

Palladium-catalyzed regioselective di- or mono-arylation of o-carboranes was achieved using weakly coordinating amides at room temperature. Therefore, a series of B(3,4)-diarylated and B(3)-monoarylated o-carboranes anchored with valuable functional groups were accessed for the first time. This strategy provided an efficient approach for the selective activation of B(3,4)–H bonds for regioselective functionalizations of o-carboranes.

Graphical abstract: Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

Supplementary files

Article information

Article type
Edge Article
Submitted
12 Mar 2020
Accepted
03 May 2020
First published
05 May 2020
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2020,11, 10764-10769

Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature

Y. Liang, L. Yang, B. B. Jei, R. Kuniyil and L. Ackermann, Chem. Sci., 2020, 11, 10764 DOI: 10.1039/D0SC01515F

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