Issue 6, 2020
From the journal:

Sustainable Energy & Fuels

A novel nonheme manganese(ii) complex for (electro) catalytic oxidation of water†

Dattaprasad D. Narulkar,‡a   Koteshwar Devulapally,‡bc   Anil Kumar U.,‡d   Sunder N. Dhuri,*a   Vishal M. Dhavale,*bcd   Anil Kumar Vardhaman ORCID logo *b  and  Lingamallu Giribabu ORCID logo *bc  

* Corresponding authors

a School of Chemical Sciences, Goa University, Goa-403206, India
E-mail: sndhuri@unigoa.ac.in

b Polymers & Functional Materials Division, CSIR-Indian Institute of Chemical Technology, Uppal Road, Tarnaka, Hyderabad-500 007, India
E-mail: anil1hnk@gmail.com, vishal.mdhavale@gmail.com, giribabu@iict.res.in

c Academy of Scientific and Innovative Research (AcSIR), Ghaziabad-201002, India

d CSIR-Central Electrochemical Research Institute, CSIR Madras Complex, Taramani, Chennai-600 113, India

Abstract

We report a newly designed single-metal-site Mn-complex (1) which is synthesized by a simple method and structurally characterized by single-crystal X-ray crystallography and other spectroscopic tools. Electrochemical water oxidation (EcWO) is performed under different physiological pH conditions and we found better activity at pH = 8 than neutral and acidic pH.

Graphical abstract: A novel nonheme manganese(ii) complex for (electro) catalytic oxidation of water

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Article information

DOI
https://doi.org/10.1039/D0SE00232A
Article type
Communication
Submitted
12 Feb 2020
Accepted
12 Mar 2020
First published
12 Mar 2020

Sustainable Energy Fuels, 2020,4, 2656-2660

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A novel nonheme manganese(II) complex for (electro) catalytic oxidation of water

D. D. Narulkar, K. Devulapally, A. K. U., S. N. Dhuri, V. M. Dhavale, A. K. Vardhaman and L. Giribabu, Sustainable Energy Fuels, 2020, 4, 2656 DOI: 10.1039/D0SE00232A

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