Issue 16, 2020

Photothermally induced in situ double emulsion separation by a carbon nanotube/poly(N-isopropylacrylamide) modified membrane with superwetting properties

Abstract

The use of superwetting materials has been regarded as a satisfactory approach to treat simple oil/water emulsions in recent years. However, they are still incapable of handling double emulsions with a multilayer structure. Here, we coated carbon nanotubes (CNTs) and poly(N-isopropylacrylamide) (PNIPAAm) on a poly(vinylidene fluoride) membrane, realizing photothermally induced in situ separation of double emulsions (oil-in-water-in-oil emulsions or water-in-oil-in-water emulsions) with high separation efficiency. By integrating the photo-thermal conversion properties of CNTs and the thermal isomerization properties of PNIPAAm, reversible photothermally controlled wettability transition properties were achieved. The material exhibits high hydrophobicity with a ∼145° water contact angle (WCA) under IR, and exhibits superhydrophilicity with ∼10.0° WCA without IR. Importantly, the CNT dominated liquid evaporation under IR could ensure membrane anti-pollution and permeability, thus realizing in situ separation. Theoretical calculation indicates the significance of the hydrogen bond during the photothermal response. As far as we know, this facile strategy is the first to realize in situ double emulsion separation, and shows guiding significance in smart interfacial design as well as intelligent separation applications.

Graphical abstract: Photothermally induced in situ double emulsion separation by a carbon nanotube/poly(N-isopropylacrylamide) modified membrane with superwetting properties

Supplementary files

Article information

Article type
Communication
Submitted
13 Mar 2020
Accepted
01 Apr 2020
First published
01 Apr 2020

J. Mater. Chem. A, 2020,8, 7677-7686

Photothermally induced in situ double emulsion separation by a carbon nanotube/poly(N-isopropylacrylamide) modified membrane with superwetting properties

R. Qu, X. Li, W. Zhang, Y. Liu, H. Zhai, Y. Wei and L. Feng, J. Mater. Chem. A, 2020, 8, 7677 DOI: 10.1039/D0TA02919J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements