The key mechanism of conductivity in PEDOT:PSS thin films exposed by anomalous conduction behaviour upon solvent-doping and sulfuric acid post-treatment†
Abstract
The high conductivity of initially solvent-doped poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) thin films is reduced unexpectedly upon immersion in sulfuric acid, forming a new morphology type introduced as a “patchy” grain morphology. Correlating the intra-grain structural parameters and grain morphology via spectroscopy and atomic force microscopy quantification and using a comprehensive 3D crystalline structural model, it is revealed that the slow PEDOT interchain charge transport, dictated by the π–π stacking distance and abundance within each grain, is the primary factor controlling the overall conductivity, while the grain morphology has a weaker influence.
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