A stereolithographic 3D printing method was used to fabricate spin crossover–polymer composite materials with various shapes and sizes (up to several cm). The thermomechanical properties of the polymer and the stiumuli-responsive properties of the filler are preserved in the composite – affording for a new approach of 4D printing.
M. Piedrahita-Bello, J. E. Angulo-Cervera, R. Courson, G. Molnár, L. Malaquin, C. Thibault, B. Tondu, L. Salmon and A. Bousseksou, J. Mater. Chem. C, 2020, 8, 6001 DOI: 10.1039/D0TC01532F
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