A mixed-ligand bis(dithiolene) gold complex is isolated from scrambling reaction of two neutral radical symmetric complexes. Its asymmetric character translates into specific structural and electronic properties including larger electrochemical and optical band gaps than those of both precursors.
R. Perochon, F. Barrière, O. Jeannin, L. Piekara-Sady and M. Fourmigué, Chem. Commun., 2021, 57, 1615 DOI: 10.1039/D0CC07602C
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