Self-sorting of porous Cu4L2L′2 metal–organic cages composed of isomerisable ligands†
Adrian W.
Markwell-Heys, 
a
Matthew L.
Schneider,
a
Jenica Marie L.
Madridejos,
a
Gregory F.
Metha
a
and
Witold M.
Bloch
*a
a
Matthew L.
Schneider,
a
Jenica Marie L.
Madridejos,
a
Gregory F.
Metha
a
and
Witold M.
Bloch
*a
Abstract
We report the self-sorting of a dynamic combinatorial library (DCL) of metal–organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu4L2L′2 cages that display differing porosities based on their overall shape and ligand configuration.
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