Issue 38, 2021

Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces

Abstract

We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates.

Graphical abstract: Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces

Supplementary files

Article information

Article type
Communication
Submitted
13 Jan 2021
Accepted
05 Apr 2021
First published
13 Apr 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 4694-4697

Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces

S. J. Nemat, D. Van den Eynden, L. Deblock, M. Heilmann, J. M. Köster, M. Parvizian, K. Tiefenbacher and J. De Roo, Chem. Commun., 2021, 57, 4694 DOI: 10.1039/D1CC00223F

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