A large copper-niobate cluster with the pagoda-shaped subunit {Nb20O59}

Zhijie Liang; Yuanyuan Qiao; Xue Li; Pengtao Ma; Jingyang Niu; Jingping Wang

doi:10.1039/D1CC00758K

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A large copper-niobate cluster with the pagoda-shaped subunit {Nb₂₀O₅₉}†

Zhijie Liang,^ab Yuanyuan Qiao,^a Xue Li,^a Pengtao Ma,

^a Jingyang Niu

*^a and Jingping Wang

*^a

Author affiliations

* Corresponding authors

^a Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, P. R. China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: +86-371-23886876

^b College of Textiles and Clothing, Nantong University, Nantong 226019, Jiangsu, P. R. China

Abstract

A 72-nuclearity niobium cluster was synthesized, in which two {CuNb₂₆O₇₆} clusters and one {Nb₂₀O₅₉} cluster are fused in a triangular fashion, resulting in a {Nb₁₂} cavity. Further, the simple nature of the species allowed its investigation by ESI-MS analysis, yielding two subunits with time.

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Article information

DOI: https://doi.org/10.1039/D1CC00758K
Article type: Communication
Submitted: 09 Feb 2021
Accepted: 16 Mar 2021
First published: 17 Mar 2021

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Chem. Commun., 2021,57, 3999-4002

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A large copper-niobate cluster with the pagoda-shaped subunit {Nb₂₀O₅₉}

Z. Liang, Y. Qiao, X. Li, P. Ma, J. Niu and J. Wang, Chem. Commun., 2021, 57, 3999 DOI: 10.1039/D1CC00758K

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Chemical Communications