The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene

Nasrina Parvin; Nilanjana Sen; Puthan Veetil Muhasina; Srinu Tothadi; Pattiyil Parameswaran; Shabana Khan

doi:10.1039/D1CC01034D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

The diverse reactivity of NOBF₄ towards silylene, disilene, germylene and stannylene†

Nasrina Parvin,^a Nilanjana Sen,^a Puthan Veetil Muhasina,

^b Srinu Tothadi,

^c Pattiyil Parameswaran

*^b and Shabana Khan

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Science Education and Research Pune, Dr Homi Bhabha Road, Pashan, Pune-411008, India
E-mail: shabana@iiserpune.ac.in

^b Department of Chemistry, National Institute of Technology Calicut, NIT Campus P. O., Calicut – 673601, India
E-mail: param@nitc.ac.in

^c Organic Chemistry Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India

Abstract

The reactivity of NOBF₄ towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)₂E(= O → BF₃)N(SiMe₃)₂, E = Si (3) and Ge (4)] were accomplished from the corresponding tetrylenes. An unusual heterocycle (10) featuring B, Sn, N, P, and O atoms was obtained from the reaction with a stannylene, while a 1,2-vicinal anti addition of fluoride was observed with a disilene (12).

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1CC01034D
Article type: Communication
Submitted: 23 Feb 2021
Accepted: 27 Apr 2021
First published: 27 Apr 2021

Download Citation

Chem. Commun., 2021,57, 5008-5011

Permissions

Request permissions

The diverse reactivity of NOBF₄ towards silylene, disilene, germylene and stannylene

N. Parvin, N. Sen, P. V. Muhasina, S. Tothadi, P. Parameswaran and S. Khan, Chem. Commun., 2021, 57, 5008 DOI: 10.1039/D1CC01034D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications