Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH3)3SOPbI3

Yuki Tanaka; Shiqiang Bai; Xizu Wang; Si Yin Tee; Siew Lay Lim; Lin Ke; Surani B. Dolmanan; Coryl Jing Jun Lee; Poh Chong Lim; Xiang Yao; Jishan Wu; Ming-Yong Han

doi:10.1039/D1CC01386F

Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH₃)₃SOPbI₃†

Yuki Tanaka,‡^ab Shiqiang Bai,‡^a Xizu Wang,‡^a Si Yin Tee,^a Siew Lay Lim,^a Lin Ke,^a Surani B. Dolmanan,^a Coryl Jing Jun Lee,^a Poh Chong Lim,^a Xiang Yao,^c Jishan Wu

*^b and Ming-Yong Han

*^ac

Author affiliations

* Corresponding authors

^a Institute of Materials Research and Engineering, A*STAR, Singapore
E-mail: my-han@imre.a-star.edu.sg

^b Department of Chemistry, National University of Singapore, Singapore
E-mail: chmwuj@nus.edu.sg

^c Institute of Molecular Plus, Tianjin University, Tianjin 300072, P. R. China
E-mail: han_mingyong@tju.edu.cn

Abstract

We report the synthesis and optical and electronic properties of a one-dimensional sulfoxonium-based hybrid metal halide in an orthorhombic crystal system with a Pnma space group. To provide direct insights, a method is developed to calculate tolerance factors with the ionic radii of non-spherical cations from X-ray crystallographic data.

Chemical Communications

Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH₃)₃SOPbI₃†

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Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH₃)₃SOPbI₃

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