Issue 56, 2021
From the journal:

Chemical Communications

Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design†

Hong-Mei Pan,ab   Qian-Lu Yang,a   Xin-Xin Xing,a   Jia-Peng Li,a   Fan-Lei Meng,a   Xin Zhang,a   Pan-Chao Xiao,a   Cheng-Yang Yue*a  and  Xiao-Wu Lei ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong, P. R. China
E-mail: yuechengyang@126.com, xwlei_jnu@163.com

b College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, P. R. China

Abstract

Five new zero-dimensional hybrid manganese halides based on discrete [MnCl4]2− tetrahedrons were prepared and used as highly efficient green-light emitters. Through rational management of organic cations to tailor the Mn⋯Mn separation distances between neighboring [MnCl4]2− tetrahedrons, the photoluminescence quantum yield increased significantly from 7.98% to 81.11%.

Graphical abstract: Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design

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Article information

DOI
https://doi.org/10.1039/D1CC02353E
Article type
Communication
Submitted
03 May 2021
Accepted
07 Jun 2021
First published
07 Jun 2021

Chem. Commun., 2021,57, 6907-6910

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Enhancement of the photoluminescence efficiency of hybrid manganese halides through rational structural design

H. Pan, Q. Yang, X. Xing, J. Li, F. Meng, X. Zhang, P. Xiao, C. Yue and X. Lei, Chem. Commun., 2021, 57, 6907 DOI: 10.1039/D1CC02353E

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