Probing optical and magnetic properties via subtle stereoelectronic effects in mononuclear DyIII-complexes

Alexandros A. Kitos; Diogo A. Gálico; Niki Mavragani; Raúl Castañeda; Jani O. Moilanen; Jaclyn L. Brusso; Muralee Murugesu

doi:10.1039/D1CC02407H

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Probing optical and magnetic properties via subtle stereoelectronic effects in mononuclear Dy^III-complexes†

Alexandros A. Kitos,

^a Diogo A. Gálico,^a Niki Mavragani,

^a Raúl Castañeda,^a Jani O. Moilanen,

*^b Jaclyn L. Brusso

*^a and Muralee Murugesu

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada
E-mail: jbrusso@uottawa.ca, m.murugesu@uottawa.ca

^b Department of Chemistry, Nanoscience Centre, University of Jyväskylä, P.O. Box 35, FI-40014, Finland
E-mail: jani.o.moilanen@jyu.fi

Abstract

Tapping into the secondary coordination environment of mononuclear Dy^III-complexes leads to drastic changes in luminescence and magnetism. Visualization of effects induced by stereoelectronics on the opto-magnetic properties was achieved through subtle modifications in the ligand framework.

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Article information

DOI: https://doi.org/10.1039/D1CC02407H
Article type: Communication
Submitted: 06 May 2021
Accepted: 07 Jul 2021
First published: 07 Jul 2021

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Chem. Commun., 2021,57, 7818-7821

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Probing optical and magnetic properties via subtle stereoelectronic effects in mononuclear Dy^III-complexes

A. A. Kitos, D. A. Gálico, N. Mavragani, R. Castañeda, J. O. Moilanen, J. L. Brusso and M. Murugesu, Chem. Commun., 2021, 57, 7818 DOI: 10.1039/D1CC02407H

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