The controllable synthesis of urchin-shaped hierarchical superstructure MOFs with high catalytic activity and stability†
Abstract
A novel dissolution–crystallization-attachment strategy was developed to synthesize urchin-shaped superstructure metal–organic frameworks (MOFs) with self-assembled one-dimensional nanorods. The superstructure MOFs not only inherited the high activity of nanosized MOFs but also displayed the high stability of microsized MOFs.