[Fe15]: a frustrated, centred tetrakis hexahedron

Daniel J. Cutler; Mukesh K. Singh; Gary S. Nichol; Marco Evangelisti; Jürgen Schnack; Leroy Cronin; Euan K. Brechin

doi:10.1039/D1CC03919A

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[Fe₁₅]: a frustrated, centred tetrakis hexahedron†

Daniel J. Cutler,

^a Mukesh K. Singh,

^a Gary S. Nichol,

^a Marco Evangelisti,

^b Jürgen Schnack,

*^c Leroy Cronin

*^d and Euan K. Brechin

*^a

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, Scotland, UK
E-mail: ebrechin@ed.ac.uk

^b Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC – Universidad de Zaragoza, 50009 Zaragoza, Spain

^c Fakultät für Physik, Universität Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany
E-mail: jschnack@uni-bielefeld.de

^d School of Chemistry, The University of Glasgow, Joseph Black Building, Glasgow, Scotland, UK
E-mail: lee.cronin@glasgow.ac.uk

Abstract

The combination of two different Fe^III salts in a solvothermal reaction with triethanolamine results in the formation of a high symmetry [Fe^III₁₅] cluster whose structure conforms to a centred, tetrakis hexahedron.

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Article information

DOI: https://doi.org/10.1039/D1CC03919A
Article type: Communication
Submitted: 20 Jul 2021
Accepted: 09 Aug 2021
First published: 09 Aug 2021
This article is Open Access

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Chem. Commun., 2021,57, 8925-8928

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[Fe₁₅]: a frustrated, centred tetrakis hexahedron

D. J. Cutler, M. K. Singh, G. S. Nichol, M. Evangelisti, J. Schnack, L. Cronin and E. K. Brechin, Chem. Commun., 2021, 57, 8925 DOI: 10.1039/D1CC03919A

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