Issue 79, 2021
From the journal:

Chemical Communications

A ring of grids: a giant spin-crossover cluster†

Takuya Shiga, ORCID logo *a   Minami Tachibana,a   Hajime Sagayama,b   Reiji Kumai, ORCID logo b   Graham N. Newton, ORCID logo c   Hiroki Oshio ORCID logo ad  and  Masayuki Niheia  

* Corresponding authors

a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
E-mail: shiga@chem.tsukuba.ac.jp

b Photon Factory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Oho 1-1, Tsukuba, Ibaraki 305-0801, Japan

c GSK Carbon Neutral Laboratories for Sustainable Chemistry, University of Nottingham, Nottingham, UK

d State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., 116024 Dalian, China

Abstract

Mononuclear and icosanuclear spin-crossover complexes, [FeII(HL)2](BF4)2 (1) and [FeII20(L)24](BF4)16 (2), were synthesized using an asymmetric multidentate ligand (HL). 1 has a bis-chelate structure with two protonated ligands, while 2 has a ring-shape structure comprising four [2 × 2] grid moieties and four mononuclear units.

Graphical abstract: A ring of grids: a giant spin-crossover cluster

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Article information

DOI
https://doi.org/10.1039/D1CC04346C
Article type
Communication
Submitted
09 Aug 2021
Accepted
06 Sep 2021
First published
13 Sep 2021

Chem. Commun., 2021,57, 10162-10165

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A ring of grids: a giant spin-crossover cluster

T. Shiga, M. Tachibana, H. Sagayama, R. Kumai, G. N. Newton, H. Oshio and M. Nihei, Chem. Commun., 2021, 57, 10162 DOI: 10.1039/D1CC04346C

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