Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids

Shengbiao Tang; Peng Zhang; Changkai Wang; Ying Shao; Jiangtao Sun

doi:10.1039/D1CC04861A

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Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids†

Shengbiao Tang,

*^a Peng Zhang,^a Changkai Wang,^a Ying Shao^a and Jiangtao Sun

*^a

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* Corresponding authors

^a Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
E-mail: shengbiaotang@cczu.edu.cn, jtsun@cczu.edu.cn

Abstract

We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols using free carboxylic acids as nucleophiles under mild conditions with broad functional group tolerance, exhibiting excellent regio- and enantioselectivity .

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Article information

DOI: https://doi.org/10.1039/D1CC04861A
Article type: Communication
Submitted: 31 Aug 2021
Accepted: 29 Sep 2021
First published: 30 Sep 2021

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Chem. Commun., 2021,57, 11080-11083

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Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids

S. Tang, P. Zhang, C. Wang, Y. Shao and J. Sun, Chem. Commun., 2021, 57, 11080 DOI: 10.1039/D1CC04861A

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Chemical Communications

Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids†

Abstract

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Iridium-catalyzed regio- and enantioselective allylic esterification of secondary allylic alcohols with carboxylic acids

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