Pd-catalyzed allylative dearomatisation of naphthyl halides is shown to be feasible by employing Grignard reagents. The high reactivity of the nucleophile allows for fast reactions and low catalyst loading, while a plethora of successfully substituted compounds illustrate the broad scope. Five membered heteroaromatic compounds are also demonstrated to be reactive under similar conditions.
C. Boldrini and S. R. Harutyunyan, Chem. Commun., 2021, 57, 11807 DOI: 10.1039/D1CC05609C
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