The electronic effect of tert-butyl groups on intramolecular through-bond interactions between redox units in tetrathiafulvalene-tetraazapyrene (TAP) triads is investigated. The insertion of tert-butyl groups raises the TAP-localised LUMO level by 0.21 eV, in fairly good agreement with 0.17 eV determined by DFT calculations.
P. Zhou, U. Aschauer, S. Decurtins, T. Feurer, R. Häner and S. Liu, Chem. Commun., 2021, 57, 12972 DOI: 10.1039/D1CC05671A
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