Snowflake porous multi-metal oxide nanocatalysts from metallocene@metal organic framework precursors

Ignacio Luz; Sameer Parvathikar; Michael Carpenter; Brittany Grillo; John Carpenter; Marty Lail

doi:10.1039/D0CE01666G

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Snowflake porous multi-metal oxide nanocatalysts from metallocene@metal organic framework precursors†

Ignacio Luz,

*^a Sameer Parvathikar,^a Michael Carpenter,^a Brittany Grillo,^a John Carpenter^a and Marty Lail^a

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* Corresponding authors

^a RTI International, 3040 E. Cornwallis Rd, RTP, North Carolina, USA
E-mail: iluzminguez@rti.org

Abstract

We report a general approach to prepare ‘snowflake’ porous metal oxide nanostructured catalysts using tailored precursors consisting of metallocenes embedded within MOFs via thermal treatment under air. The resulting well-dispersed multi-metallic nanocatalysts show improved activity for ammonia synthesis at low temperature.

This article is part of the themed collection: Crystal Engineering Techniques

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DOI: https://doi.org/10.1039/D0CE01666G
Article type: Communication
Submitted: 17 Nov 2020
Accepted: 16 Dec 2020
First published: 16 Dec 2020

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CrystEngComm, 2021,23, 533-537

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Snowflake porous multi-metal oxide nanocatalysts from metallocene@metal organic framework precursors

I. Luz, S. Parvathikar, M. Carpenter, B. Grillo, J. Carpenter and M. Lail, CrystEngComm, 2021, 23, 533 DOI: 10.1039/D0CE01666G

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CrystEngComm

Snowflake porous multi-metal oxide nanocatalysts from metallocene@metal organic framework precursors†

Abstract

Supplementary files

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Snowflake porous multi-metal oxide nanocatalysts from metallocene@metal organic framework precursors

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