Ruthenium-catalysed domino hydroformylation–hydrogenation–esterification of olefins

Abstract

A novel catalytic domino reductive hydroformylation–esterification of olefins is reported. The optimal protocol makes use of an inexpensive Ru carbonyl catalyst and uses acetic acid as both solvent and reactant. In general, moderate to good yields are obtained using aliphatic or aromatic olefins including industrially relevant di-isobutene. This atom-efficient catalytic transformation provides straightforward access to various acetate esters from unfunctionalized olefins.