The construction of dynamic dysprosium-carboxylate ribbons by utilizing the hybrid-ligand conception

Abstract

By utilizing the hybrid-ligand conception, three novel dysprosium complexes Dy(2-py-4-pmc)(L)(H₂O) (H2-py-4-pmc = 2-(2-pyridyl)pyrimidine-4-carboxylic acid; L = fumarate (fum, 1), succinate (suc, 2), or pimelate (pim, 3)) have been successfully synthesized. Structural analysis reveals that the dicarboxylate ligands connect 2-py-4-pmc⁻-protected Dy³⁺ to form one-dimensional molecular ribbons. Magnetic measurements indicate that the three complexes exhibit typical slow magnetic relaxation under a zero dc field with effective reversal barriers U_eff of 180 K, 145 K and 137 K for 1–3, respectively, which is mainly attributed to the strong Ising anisotropy of dysprosium ions induced by the appropriate arrangement of carboxylate groups. Ab initio calculations demonstrate that the charge distribution around dysprosium ions and the magnetic interactions between them are key contributions to their different dynamic behaviour.