Nonbenzenoid aromaticity of 1-phosphafulvenes: synthesis of phosphacymantrenes

Abstract

The coordination chemistry of 1-phosphafulvenes was investigated by employing their [6 + 4] adducts or α-C₂-bridged biphospholes as a precursor. Unbridged phosphacymantrenes arise from 1-phosphafulvenes via proton abstraction. α-C₂-bridged biphosphacymantrenes are probably yielded by the reductive coupling of 1-phosphafulvene with Mn₂(CO)₁₀. The coordination behavior of 1-phosphafulvenes is comparable to that of pentafulvenes, which again demonstrates the phosphorus-carbon analogy in low-coordinate organophosphorus chemistry.