Solid-phase synthesis of peptide Mn(I)–carbonyl bioconjugates and their CO release upon visible light activation

Yi Zhou; Yonglu Chen; Chunmao He

doi:10.1039/D1DT00395J

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Solid-phase synthesis of peptide Mn(i)–carbonyl bioconjugates and their CO release upon visible light activation†

Yi Zhou,

‡^a Yonglu Chen ‡^a and Chunmao He

*^a

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: hecm@scut.edu.cn

Abstract

A one-pot synthetic route has been developed for the assembly of peptide Mn(I)–carbonyl bioconjugates. It allows the installation of a variety of chelating agents at the late stage, and after just one purification step the TAT–MnCO complexes can be obtained. The resulting bioconjugates showed different and tunable CO releasing kinetics upon visible light activation.

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Article information

DOI: https://doi.org/10.1039/D1DT00395J
Article type: Paper
Submitted: 04 Feb 2021
Accepted: 11 Feb 2021
First published: 21 Feb 2021

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Dalton Trans., 2021,50, 4231-4236

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Solid-phase synthesis of peptide Mn(I)–carbonyl bioconjugates and their CO release upon visible light activation

Y. Zhou, Y. Chen and C. He, Dalton Trans., 2021, 50, 4231 DOI: 10.1039/D1DT00395J

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Dalton Transactions

Solid-phase synthesis of peptide Mn(i)–carbonyl bioconjugates and their CO release upon visible light activation†

Abstract

Supplementary files

Article information

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Solid-phase synthesis of peptide Mn(I)–carbonyl bioconjugates and their CO release upon visible light activation

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