Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(III)-based 2D MOF

Marta Orts-Arroyo; Renato Rabelo; Ainoa Carrasco-Berlanga; Nicolás Moliner; Joan Cano; Miguel Julve; Francesc Lloret; Giovanni De Munno; Rafael Ruiz-García; Júlia Mayans; José Martínez-Lillo; Isabel Castro

doi:10.1039/D1DT00462J

Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(iii)-based 2D MOF†

Marta Orts-Arroyo,^a Renato Rabelo,^a Ainoa Carrasco-Berlanga,^a Nicolás Moliner,^a Joan Cano,

^a Miguel Julve,^a Francesc Lloret,^a Giovanni De Munno,

^b Rafael Ruiz-García,^a Júlia Mayans,

*^a José Martínez-Lillo

*^a and Isabel Castro

*^a

Author affiliations

* Corresponding authors

^a Instituto de Ciencia Molecular (ICMol), Universitat de València, c/José Beltrán 2, 46980 Paterna (València), Spain
E-mail: julia.mayans@qi.ub.edu, f.jose.martinez@uv.es, isabel.castro@uv.es

^b Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, 87030 Arcavacata di Rende, Cosenza, Italy

Abstract

The coexistence of field-induced slow magnetic relaxation and moderately large magnetocaloric efficiency in the supra-Kelvin temperature region occurs in the 2D compound [Gd^III₂(ox)₃(H₂O)₆]_n·4nH₂O (1), a feature that can be exploited in the proof-of-concept design of a new class of slow-relaxing magnetic materials for cryogenic magnetic refrigeration.

Dalton Transactions

Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(iii)-based 2D MOF†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Field-induced slow magnetic relaxation and magnetocaloric effects in an oxalato-bridged gadolinium(III)-based 2D MOF

Social activity

Search articles by author

Spotlight

Advertisements