Broadened bioactivity and enhanced durability of two structurally distinct metal–organic frameworks containing Zn2+ ions and thiabendazole

Daiya Kobayashi; Akira Hamakawa; Yuki Yamaguchi; Toshiaki Takahashi; Mitsuhiro Yanagita; Shigebumi Arai; Mao Minoura

doi:10.1039/D1DT00733E

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Broadened bioactivity and enhanced durability of two structurally distinct metal–organic frameworks containing Zn²⁺ ions and thiabendazole†

Daiya Kobayashi,

*^a Akira Hamakawa,^a Yuki Yamaguchi,^a Toshiaki Takahashi,^a Mitsuhiro Yanagita,^a Shigebumi Arai^a and Mao Minoura

*^b

Author affiliations

* Corresponding authors

^a Nippon Soda Co. Ltd., Chiba Research Center, 12-54 Goi-minamikaigan, Ichihara, Chiba 290-0045, Japan
E-mail: d.kobayashi@nissogr.com

^b College of Science, Department of Chemistry, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo, Japan
E-mail: minoura@rikkyo.ac.jp

Abstract

Novel metal–organic frameworks (MOFs) based on thiabendazole (TBZ) were developed. The two structurally distinct TBZ-MOFs synthesized in this study exhibited enhanced durability and a broader biocidal spectrum than either individual bioactive species (i.e., Zn²⁺ and TBZ). The characteristics of each TBZ-MOF are related to the coordination modes among the Zn²⁺ ions and ligand donors. The difference in water solubility between the two TBZ-MOFs due to the structural design allows for the controlled release of the desired bioactive component.

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Article information

DOI: https://doi.org/10.1039/D1DT00733E
Article type: Communication
Submitted: 04 Mar 2021
Accepted: 22 Mar 2021
First published: 31 Mar 2021

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Dalton Trans., 2021,50, 7176-7180

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Broadened bioactivity and enhanced durability of two structurally distinct metal–organic frameworks containing Zn²⁺ ions and thiabendazole

D. Kobayashi, A. Hamakawa, Y. Yamaguchi, T. Takahashi, M. Yanagita, S. Arai and M. Minoura, Dalton Trans., 2021, 50, 7176 DOI: 10.1039/D1DT00733E

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Dalton Transactions