Multifunctional MOF-based probes for efficient detection and discrimination of Pb2+, Fe3+ and Cr2O72−/CrO42−

Abstract

Developing metal–organic framework (MOF)-based fluorescent probes for efficient detection and discrimination of polluting ions in groundwater is vital for environmental protection and human health. In this paper, we prepared two luminescence-active transition MOFs, namely, Zn-MOF and Cd-MOF, and conducted sensing experiments. The results show that they both exhibit multiple-target detection for Fe³⁺, Pb²⁺ and Cr(VI) with high sensitivity, good anti-interference ability and good recyclability even with different frameworks. In addition, Eu³⁺-incorporated samples, Eu³⁺@MOFs, with dual-emission have been fabricated via efficient encapsulation of Eu³⁺ ions into the MOF host. As expected, Eu³⁺@MOF hybrids also act as multi-target and self-calibrated probes to selectively detect Fe³⁺ and Cr(VI) ions. However, the quenching efficiencies of the original MOFs towards Fe³⁺ are higher than those of Eu³⁺@MOFs. Thus, we could differentiate Fe³⁺, Pb²⁺ and Cr(VI) ions by comparing the changes of fluorescence emission between Eu³⁺@MOFs and the original MOFs. The recognition mechanism may be attributed to the competitive energy absorption between MOFs or Eu³⁺@MOFs and the analytes.