Issue 26, 2021
From the journal:

Dalton Transactions

Bis(imino)carbazolate lead(ii) fluoride and related halides†

Peter M. Chapple, ORCID logo a   Ghanem Hamdoun,b   Thierry Roisnel, ORCID logo a   Jean-François Carpentier, ORCID logo a   Hassan Oulyadi ORCID logo c  and  Yann Sarazin ORCID logo *a  

* Corresponding authors

a Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, Rennes F-35000, France
E-mail: yann.sarazin@univ-rennes1.fr
Tel: +33 223-233019

b Euromed University of Fes (UEMF), Fez, Morocco

c Normandie Université, UNIROUEN, INSA de Rouen, CNRS, Laboratoire COBRA (UMR 6014 & FR 3038), 76000 Rouen, France

Abstract

The versatility of a bulky bis(imino)carbazolate ligand in lead(II) chemistry is illustrated by the synthesis of a soluble, heteroleptic lead(II) fluoride and several halide (Cl, Br and I), amide and hydrocarbyl congeners. All complexes have been structurally authenticated, and a full set of 207Pb NMR data is discussed.

Graphical abstract: Bis(imino)carbazolate lead(ii) fluoride and related halides

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Article information

DOI
https://doi.org/10.1039/D1DT01615F
Article type
Communication
Submitted
18 May 2021
Accepted
24 May 2021
First published
04 Jun 2021

Dalton Trans., 2021,50, 9021-9025

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Bis(imino)carbazolate lead(II) fluoride and related halides

P. M. Chapple, G. Hamdoun, T. Roisnel, J. Carpentier, H. Oulyadi and Y. Sarazin, Dalton Trans., 2021, 50, 9021 DOI: 10.1039/D1DT01615F

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